HOMOGENEOUS CATALYSIS:Enhanced: Toward Greener Chemistry

Toward greener nanosynthesis.

The Baeyer-Villiger reaction: new developments toward greener procedures.

Iron(III) Fluorinated Porphyrins: Greener Chemistry from Synthesis to Oxidative Catalysis Reactions.

Iron(III) fluorinated porphyrins play a central role in the biomimetics of heme enzymes and enable cleaner routes to the oxidation of organic compounds. The present work reports significant improvements in the eco-compatibility of the synthesis of 5,10,15,20-tetrakis-pentafluorophenylporphyrin (H₂TPFPP) and the corresponding iron complex [Fe(TPFPP)Cl], and the use of [Fe(TPFPP)Cl] as an oxidati...

Routes to greener plastics

How to hide a dimension from view Compacted dimensions are essential ingredients of advanced string theories; the extra dimensions used to describe the world are hidden from view, or compacted. Pendry et al. used concepts of transformation optics, in which metamaterials are designed to produce specific optical properties, to show theoretically that compacted dimensions could be possible in plas...

Infrared Irradiation: Toward Green Chemistry, a Review.

This review provides a comprehensive overview of where infrared irradiation has been employed, mainly as regards activating green mode for natural products extractions, as well as to favor a reaction, highlighting its actual importance. It is also underlined that infrared irradiation heating has been around for a long time; however, only in the last eighteen years have many of its advantages be...